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Not forgetting the issue here folks...yes you can go to local gunshop and buy ammo. That is not an activating event.
My question was...that if buying online then you need a Police Mail Order Form...

Oh Bum! That's OK...I can get ammo locally anyway.
Just thought I might try some different makes of rimfire ammo.
Thanks guys.

OK, buying ammo isn't an activating event for the firearms registry.
But how about an online purchase? You need to get the Police form sorted out and that means you have interacted with the Police....