I've had a pair of Lowa Ticams for the last 8 years and will be getting them resoled after the roar/Winter hunting. They've been a very good boot for me so I don't have experience with anything else. However I like leather as it's waterproof and lasts well if you look after it.
Definitely try a few different pairs on though and pick what is comfortable. Ideally walk around for at least 30min before hand as your feet always swell up a bit when you're walking as opposed to sitting down.
No matter what brand you get make sure you look after it, any (leather) boot will start cracking and pulling stiching if it's sat right next to the fire to dry or left in the Ute dirty after a day in the stock yards.
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