If you put the NF on your .22, it will be a good one for the initial practice that people have suggested, it will be a bit marginal for the longer stuff that you want to do with the 6.5, but you can cross that bridge when you get there.
Practicing trigger control is a good move, but if you do it with a rimfire, make sure to use snap caps, dry firing a rimfire will cause eventually cause damage.
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